Villa's return to the top level of European football after a 41-year wait began successfully with a 3-0 win at Swiss side Young Boys two weeks ago.
But Villa Park's first taste of the competition since it was re-branded as the Champions League brings back memories of the club's greatest-ever night.
Villa upset the odds to beat a mighty Bayern side, featuring club legends Paul Breitner and Karl-Heinz Rummenigge, 1-0 in Rotterdam.
"It is a special, special match for everyone," said Emery at his pre-match press conference on Tuesday.
"We are motivated and so excited to play tomorrow with our supporters in Villa Park. Remembering as well the final that Villa played against them 42 years ago."
Emery, who has won the Europa League four times in his managerial career, has inspired a phenomenal turnaround in Villa's fortunes since taking charge less than two years ago.
They were battling relegation from the Premier League when the Spaniard replaced Steven Gerrard, but rose to finish seventh in Emery's first season to qualify for the Europa Conference League.
Villa reached the semi-finals in their first experience of European football for 13 years and secured a top-four finish in the Premier League, above Chelsea, Manchester United and Tottenham, to qualify for the Champions League.
In-form Bayern
Bayern, six-time European champions, are unbeaten in seven matches since Vincent Kompany took charge and Emery believes they are among the favourites to win the Champions League.
But he is hoping his side can compete as they have done with the Premier League's elite sides in recent seasons.
"I want to play matches like this and I want to play consistently matches like this," added Emery.
"In the Premier League we are facing teams like them - Manchester City, Liverpool, Arsenal - that can win this competition this year. They are favourites with other teams like Bayern Munich.
"Playing in Europe, we are very, very happy to face Bayern at home and hopefully we can enjoy tomorrow. Hopefully we can compete and show our best against them."
Kompany was a surprise choice by Bayern to succeed Thomas Tuchel after he oversaw Burnley's relegation from the Premier League last season.
However, Emery is not surprised at the fast start the former Manchester City captain has made to life in Germany.
"I think he's a coach that has a very good future and he started being successful with Burnley when he got promoted.
"Last year was difficult with Burnley at the beginning, favourites to get relegated. He didn't achieve to keep them in the Premier League, but I always respect him a lot as a coach because the two matches we played were very difficult.
"With Bayern Munich and the players they have, I think it's easier to get the level they will want to have in their league and in the Champions League. They have started winning matches with very good results, playing very well."
